R L C P
Hierarchic Classification of Catalytic Mechanisms

R 8.-.-.- : Isomerization (shift of double-bond position) (Reaction)

L 8.131.-.- : Adjacent bond; O=C-C to O-C=C (Ligand group involved)

Catalytic mechanisms

8.131.42001.- : Base-Acid/Stabilizers; Base deprotonation of initially single-bonded atom leading to intermediate formation; Intermediate stabilized; Acid protonation to initially double-bonded atom

8.131.160500.- : Base/Modulator/Stabilizer; Modulator-assisted base deprotonation of initially-single-bonded atom; Initially-double-bonded atom stabilized

8.131.161950.- : Dodecenoyl-CoA delta-isomerase 1st reaction step-like mechanism (Base/Stabilizer); Base deprotonation of initially-single-bonded atom; Initially-double-bonded atom stabilized

8.131.164850.- : GDP mannose dehydratase 2nd reaction step-like mechanism (Base/Modulator); Modulator-assisted base deprotonation of initially-single-bonded atom

8.131.581400.- : Base/Acid-Stabilizer/Stabilizer; Inorganic cofactor-assisted stabilization of adjacent atoms of central atom/initially single-bonded atom/double-bonded atom; Base deprotonation of initially single-bonded atom & Acid protonation to initially double-bonded atom

8.131.584400.- : Base/Base-Acid/Modulator; Modulator-assisted base deprotonation of initially single-bonded atom; Inorganic cofactor-assisted proton transfer by base-acid from atom adjacent to initially single-bonded atom to initially double-bonded atom

8.131.704320.- : 6-phospho-alpha-glucosidase 2nd reaction step-like mechanism (Base/Modulator); Modulator-assisted base through water & Inorganic cofactor stabilization of initially double-bonded atom and adjacent atom to initially single-bonded atom; Base deprotonation of initially single-bonded atom

8.131.705800.- : Base; Inorganic-cofactor-assisted stabilization of double-bonded atom and adjacent atom to single-bonded atom; Inorganic-cofactor-assisted activation of initially single-bonded atom; Base deprotonation of single-bonded atom

8.131.708000.- : Base/Stabilizer; Inorganic-cofactor-bound to double-bonded atom; Base deprotonation of initially single-bonded atom leading to isomerization; Stabilization of charge on finally single-bonded atom

8.131.712490.- : Glucarate dehydratase 1st reaction step-like mechanism (Base); Base deprotonation from single-bonded atom; Inorganic-cofactor stabilization of double-bonded atom

8.131.1241100.- : GDP fucose synthase 1st reaction step-like mechanism (Base/Stabilizer/Modulator); Modulation of Stabilizer through inorganic-cofactor; Base deprotonation of initially single-bonded atom; Stabilization of initially double-bonded atom